Question

【題目】已知：①Zn(s)＋O2(g)＝ZnO(s)ΔH＝－348.3kJ·mol－1

②2Ag(s)＋O2(g)＝Ag2O(s)ΔH＝－31.0kJ·mol－1

則Zn與Ag2O反應生成ZnO和Ag的熱化學方程式為

A. Zn(s)＋Ag2O(s)===ZnO(s)＋2Ag(s)ΔH＝＋317.3kJ·mol－1

B. Zn＋Ag2O===ZnO＋2Ag ΔH＝＋317.3kJ·mol－1

C. Zn(s)＋Ag2O(s)===ZnO(s)＋2Ag(s)ΔH＝－317.3kJ

D. 2Zn(s)＋2Ag2O(s)===2ZnO(s)＋4Ag(s)ΔH＝－634.6 kJ·mol－1

Answer 1

【答案】D

【解析】根據蓋斯定律，用①－②得：Zn(s)＋Ag2O(s) = ZnO(s)＋2Ag(s) ΔH＝－348.3 kJ/mol－(－31.0 kJ/mol)＝－317.3 kJ/mol，C選項單位錯誤，若增大2倍，則為：2Zn(s)＋2Ag2O(s)===2ZnO(s)＋4Ag(s)ΔH＝－634.6 kJ·mol－1，正確。答案選D。